With Australia in control, the West Indies batsmen were determined not to give their wickets away and deny the hosts a quick win.
After Kraigg Brathwaite (31) provided the only wicket of the morning session, Peter Siddle made the second-session breakthrough when he had Darren Bravo caught behind for 21.
Rajendra Chandrika opened up and played his shots before falling lbw to James Pattinson for a test career-best 37 and Marlon Samuels was caught behind for 19 off Mitchell Marsh after a slow start.
Denesh Ramdin was on 19 with Jermaine Blackwood on 16 at the break.
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